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The heterometallic Tl I /Au I  complex {[Au(C 6 F 5 ) 2 Tl] 2 (L)} n  has an unprecedented polymeric structural motif with a metallic pseudo-rhombic Au 2 Tl 2  core that repeats itself to form zig-zag polymers and shows a thermochromic behaviour.

Luminescent gold–thallium derivatives with a pyridine-containing 12-membered aza-thioether macrocycle