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Reflection absorption infrared spectroscopy (RAIRS) and first-principles density functional theory (DFT) combine to suggest a pathway for NO  x   reduction on Cu{311} involving a flat-lying N 2 O 2  intermediate.

Partial reduction of NO to N2O on Cu{311}: role of intermediate N2O2

Partial reduction of NO to N₂O on Cu{311}: role of intermediate N₂O₂