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Improving the stability of Ni-based dry reforming catalysts is a key challenge. ALD-grown Al 2 O 3  overcoats deposited onto Ni/SiO 2  prevent the sintering of Ni, reduce deactivation by coke and inhibit the formation of inactive NiAl 2 O 4  on time on stream.

catalysis science and technology

Structural insight into an atomic layer deposition (ALD) grown Al2O3 layer on Ni/SiO2: impact on catalytic activity and stability in dry reforming of methane