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Commercially available Ni( ii ) and Co( ii ) complexes – M(acac) 2  and M(tmhd) 2  – exhibit catalytic activity for alkene/vinylsilane dehydrogenative silylation ( DS ) and hydrosilylation ( HS ) with tertiary silanes without using any external reducing agents.

Ni(ii) and Co(ii) bis(acetylacetonato) complexes for alkene/vinylsilane silylation and silicone crosslinking