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As an example of symmetry breaking in NEXAFS spectra of protonated species we present a high resolution NEXAFS spectrum of protonated dinitrogen, the diazynium ion N 2 H + .

Breaking inversion symmetry by protonation: experimental and theoretical NEXAFS study of the diazynium ion, N2H+

Breaking inversion symmetry by protonation: experimental and theoretical NEXAFS study of the diazynium ion, N₂H⁺