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Total emission and CPL spectra of three 9-coordinate, C3 symmetric Eu( iii ) complexes with well-defined speciation show that their ligand fields are very sensitive to solvent polarity, even if solvent is not present in the first coordination sphere.

physical chemistry chemical physics/pccp. physical chemistry chemical physics

Striking solvent dependence of total emission and circularly polarised luminescence in coordinatively saturated chiral europium complexes: solvation significantly perturbs the ligand field