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Among the various Pd 1 Ni x  alloys ( x  = 0.33, 1 and 3) supported on nitrogen-doped carbon, Pd 1 Ni 1 /N–C has the highest activity for formic acid (HCO 2 H, FA) dehydrogenation as a result of synergistic interactions between Pd and Ni atoms.

Formic acid dehydrogenation over PdNi alloys supported on N-doped carbon: synergistic effect of Pd–Ni alloying on hydrogen release