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A series of halogen-bonded (XB) 1D and zigzag supramolecular architectures involving a sterically hindered class of homologous  para -xylenes bearing bipyridyl moieties at peripheries co-crystallized with mono-, di-, and triiodofluorobenzenes as XB donors are prepared.

Halogen-bonded one-dimensional chains of functionalized ditopic bipyridines co-crystallized with mono-, di-, and triiodofluorobenzenes