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N -Sulfonyl-1,2,3,4-triazaphospholes undergo a highly selective and unprecedented transformation to  cyclo -1,3-diphospha( iii )-2,4-diazane-Au( i ) complexes in the presence of stoichiometric amounts of AuCl·S(CH 3 ) 2  and loss of N 2 .

Au(i)-mediated N2-elimination from triazaphospholes: a one-pot synthesis of novel N2P2-heterocycles

Au(i)-mediated N₂-elimination from triazaphospholes: a one-pot synthesis of novel N₂P₂-heterocycles