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Cytochrome P450s RufS and RufM catalyse regioselective and stereoselective epoxidation and alkyl oxidation respectively, in a complex series of reactions in the biosynthesis of the antimycobacterial peptides, rufomycins.

chemical communications

<i>In vitro</i> elucidation of the crucial but complex oxidative tailoring steps in rufomycin biosynthesis enables one pot conversion of rufomycin B to rufomycin C

In vitro elucidation of the crucial but complex oxidative tailoring steps in rufomycin biosynthesis enables one pot conversion of rufomycin B to rufomycin C