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From conversions of diaryltindihydrides, Ar 2 SnH 2 , and bismuth( iii ) amide, Bi[N(SiMe 3 ) 2 ] 3 , the first representatives of mixed, uncharged Bi/Sn clusters, Bi 8 Sn 3 Ar 6  were isolated.

From organotin hydrides to heteronuclear main group metal compounds: isolation of the first neutral bismuth/tin clusters