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While the reactions of carborane-based bis-silylene with O 2 , N 2 O, and CO 2  yield the same Si 2 O 2  containing product, activations of the latter with phosphanyl-silylenyl carborane affords different products featuring SiO, PO, or CO functionalities.

chemical communications

Distinctly different reactivity of bis(silylenyl)-versus phosphanyl-silylenyl-substituted o-dicarborane towards O2, N2O and CO2