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A cationic Helicene-NHC hybrid is readily prepared and used for the construction of Rh I , Au I  and Au III  complexes. Ligand controlled chiroptical properties in the far-red spectral window are observed.

Hybrids of cationic [4]helicene and N-heterocyclic carbene as ligands for complexes exhibiting (chir)optical properties in the far red spectral window