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A mononuclear oxoiron( iv ) complex  1-trans  bearing two equatorial sulfur ligations is synthesized and characterized as an active-site model of the elusive sulfur-ligated Fe IV O intermediates in non-heme iron oxygenases.

A bioinspired oxoiron(iv) motif supported on a N2S2 macrocyclic ligand

A bioinspired oxoiron(iv) motif supported on a N₂S₂ macrocyclic ligand