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Three novel opiate surrogates with the linker at C14,  1  (6,14-AmidoHap),  2  (14-AmidoMorHap), and  3  (14-AmidoHerHap) were conjugated to tetanus toxoid (TT) and tested as heroin vaccines. The C3 and C6 moieties are crucial in antibody selectivity.

Synthesis and immunological effects of C14-linked 4,5-epoxymorphinan analogues as novel heroin vaccine haptens