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A series of supertetrahedron (ST)-based sodalite ( sod )-topology zeolitic MOFs specimens ST- sod -MOFs featuring ultramicroporous square windows and a mesoporous sodcage have been synthesized  via  a window-space-directed assembly approach.

chemical science

A window-space-directed assembly strategy for the construction of supertetrahedron-based zeolitic mesoporous metal–organic frameworks with ultramicroporous apertures for selective gas adsorption