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The first one-pot glycosylation strategy for both glycan and nucleoside synthesis based on glycosyl  ortho -(1-phenylvinyl)benzoates has been developed, which is applied to the synthesis of TMG-chitotriomycin, lipochitooligosaccharides and capuramycin.

chemical science

An orthogonal and reactivity-based one-pot glycosylation strategy for both glycan and nucleoside synthesis: access to TMG-chitotriomycin, lipochitooligosaccharides and capuramycin