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Di(2-pyridyl)ketone dimethylplatinum( ii ), (dpk)Pt II (CH 3 ) 2 , reacts with CD 3 OD at 25 °C to undergo complete deuteration of Pt–CH 3  fragments in ∼5 h without loss of methane to form (dpk)Pt II (CD 3 ) 2  in virtually quantitative yield.

chemical science

Reversible PtII–CH3 deuteration without methane loss: metal–ligand cooperation vs. ligand-assisted PtII-protonation