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Synopsis: a highly reactive Fe( iii )–NH 2  complex is generated  via  activation of ammonia or hydrazine in reactions of relevance to fundamental steps in ammonia oxidation processes mediated by an abundant, first row transition metal.

chemical science

Activation of ammonia and hydrazine by electron rich Fe(<scp>ii</scp>) complexes supported by a dianionic pentadentate ligand platform through a common terminal Fe(<scp>iii</scp>) amido intermediate

Activation of ammonia and hydrazine by electron rich Fe(ii) complexes supported by a dianionic pentadentate ligand platform through a common terminal Fe(iii) amido intermediate