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Frustration at carbon! Herein, we present a frustrated Lewis pair system derived from a water stable carbon-based Lewis acid, trioxatriangulene (TOTA + ), and a variety of Lewis bases, which successfully promotes bond cleavage and molecule fixation.

Trioxatriangulenium (TOTA+) as a robust carbon-based Lewis acid in frustrated Lewis pair chemistry

Trioxatriangulenium (TOTA⁺) as a robust carbon-based Lewis acid in frustrated Lewis pair chemistry