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We reported an IPrAuCl/AgSbF 6 -catalyzed cycloisomerization of enantio-enriched  N -1,3-disubstituted allenylindoles affording optically active pyrido[1,2- a ]-1 H -indoles in excellent yields and enantioselectivities.

Asymmetric construction of pyrido[1,2-a]-1H-indole derivatives via a gold-catalyzed cycloisomerization