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Non-luminescent crystals of [(C 6 H 11 NC) 2 Au](AsF 6 )·C 6 H 6  readily lose benzene to form the green-luminescent polymorph of [(C 6 H 11 NC) 2 Au](AsF 6 ) rather than the blue-luminescent polymorph.

chemical science

Seeing luminescence appear as crystals crumble. Isolation and subsequent self-association of individual [(C6H11NC)2Au]+ions in crystals