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Discrete (M 3 L 2 )  n  cages assembled from a tripodal ligand (L) and metal ions (M: Cu(i) or Ag(i)) are embedded in networked coordination hosts formed by partial dissociation of the same discrete cages during the crystallization process. The resulting "eggs-in-an-egg-carton" structures provide unique examples of the co-crystallization of discrete and infinite coordination frameworks.

“Eggs in egg cartons”: co-crystallization to embed molecular cages into crystalline lattices