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High proton conducting electrolytes with mechanical moldability are a key material for energy devices. We propose an approach for creating a coordination polymer (CP) glass from a protic ionic liquid for a solid-state anhydrous proton conductor. A protic ionic liquid (dema)(H 2 PO 4 ), with components which also act as bridging ligands, was applied to construct a CP glass (dema) 0.35 [Zn(H 2 PO 4 ) 2.35 (H 3 PO 4 ) 0.65 ]. The structural analysis revealed that large Zn-H 2 PO 4  - /H 3 PO 4 coordination networks formed in the CP glass. The network formation results in enhancement of the properties of proton conductivity and viscoelasticity. High anhydrous proton conductivity ( σ = 13.3 mS cm -1 at 120 °C) and a high transport number of the proton (0.94) were achieved by the coordination networks. A fuel cell with this CP glass membrane exhibits a high open-circuit voltage and power density (0.15 W cm -2 ) under dry conditions at 120 °C due to the conducting properties and mechanical properties of the CP glass.

Coordination polymer glass from a protic ionic liquid: proton conductivity and mechanical properties as an electrolyte