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A  trans -product is isolated and characterized under traditional hydroboration–oxidation conditions using Δ 5 -steroids as substrates. Experimental and theoretical studies indicate that the  trans -species occurs  via  a retro-hydroboration mechanism.

trans-Hydroboration–oxidation products in Δ5-steroids via a hydroboration-retro-hydroboration mechanism

trans-Hydroboration–oxidation products in Δ⁵-steroids via a hydroboration-retro-hydroboration mechanism