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The effect of the crystal structure of ordered transition-metal phosphide catalysts on the hydrogen-evolution reaction is investigated using single crystals of iron-phosphide (FeP) and monoclinic nickel-diphosphide ( m -NiP 2 ).

Crystallographic facet selective HER catalysis: exemplified in FeP and NiP2 single crystals

Crystallographic facet selective HER catalysis: exemplified in FeP and NiP₂ single crystals