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Tris(pyridin-2-yl)phosphoric triamide, as a metal complex and purely organic pseudopolymorphs, and the role of solvent/hydrate and substituent in the formation of the crystal packing features, along with an improved model of the MOF structure of Cu( ii )O 6  are investigated.

Coordination versus hydrogen bonds in the structures of different tris(pyridin-2-yl)phosphoric triamide derivatives