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Compared to UV alone and PMS alone systems, diclofenac was removed more efficiently in UV/PMS system at pH 7.0 due to the contribution of SO 4 ˙ −  and HO˙ and its degradation followed the pseudo-first order kinetic model.

Kinetics and reaction mechanism of photochemical degradation of diclofenac by UV-activated peroxymonosulfate