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The NbCl 5 –EtMgBr-catalyzed reaction of  N , N -disubstituted 2-alkynylamines with Et 2 Zn followed by hydrolysis or deuterolysis affords (2 Z )-alkenylamines (reduction products of alkyne) in high yields.

Niobium- and zirconium-catalyzed reactions of substituted 2 alkynylamines with Et2Zn

Niobium- and zirconium-catalyzed reactions of substituted 2 alkynylamines with Et₂Zn