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A solvent-controllable photoreaction involving 4-methoxyazobenzenes has been developed to synthesize 1-aryl-1 H -benzimidazoles or  N -arylbenzene-1,2-diamines in moderate to good yields.

rsc advances

The selective synthesis of <i>N</i>-arylbenzene-1,2-diamines or 1-arylbenzimidazoles by irradiating 4-methoxy-4′-substituted-azobenzenes in different solvents

The selective synthesis of N-arylbenzene-1,2-diamines or 1-arylbenzimidazoles by irradiating 4-methoxy-4′-substituted-azobenzenes in different solvents