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Two polymorphs and a solvatomorph of a new dimethylammonium polytungstate—decakis(dimethylammonium) dihydrogendodecatungstate, (Me 2 NH 2 ) 10 (W 12 O 42 )· n H 2 O ( n  = 10 or 11)—have been synthesized.

rsc advances

(Me2NH2)10[H2-Dodecatungstate] polymorphs: dodecatungstate cages embedded in a variable dimethylammonium cation + water of crystallization matrix