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Two TMeQ[6]-based multi-dimensional supramolecular frameworks were formed driven by weak interaction forces in the system (hydrogen bonding, C–H... π interactions, ion–dipole interactions, and dipole–dipole interactions).

Host–guest modes and supramolecular frameworks of complexes of tetramethyl cucurbit[6]uril with 4-chloroaniline and 4,4′-diaminostilbene