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The first [4 + 1] annulation reaction of  in situ -generated highly electrophilic CF 3 - ortho -quinone methides with sulphur ylides has been put forth under mild reaction conditions to access CF 3 -dihydrobenzofurans.

rsc advances

Diastereoselective synthesis of CF3-dihydrobenzofurans by [4+1] annulation of in situ-generated CF3-o-quinone methides and sulfur ylides