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The Cu( i )-catalyzed mechanism of 5-enamined-functionalized fully substituted 1,2,3-triazole synthesis was rationalized by interrupted copper( i )-catalyzed terminal alkynes and organic azides click reaction (CuAAC).

rsc advances

DFT and AFIR study on the copper(<scp>i</scp>)-catalyzed mechanism of 5-enamine-trisubstituted-1,2,3-triazole synthesis <i>via</i> C–N cross-coupling and the origin of ring-opening of 2<i>H</i>-azirines

DFT and AFIR study on the copper(i)-catalyzed mechanism of 5-enamine-trisubstituted-1,2,3-triazole synthesis via C–N cross-coupling and the origin of ring-opening of 2H-azirines