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The facile synthesis of tetrahydroquinoline-based chiral carbene precursors is reported. A rare Au⋯H–C(sp 3 ) interaction between Au( i ) and the hydrogen atom was observed in the crystal structure of a related NHC–gold complex.

Syntheses of tetrahydroquinoline-based chiral carbene precursors and the related chiral NHC–Au(i) complex