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A novel core@double-shell acidic nanocatalyst (Fe 3 O 4 @SiO 2 @RF–SO 3 H) was prepared, characterized and applied in catalytic one-pot condensation between aromatic aldehydes, dimedone, malononitrile, and ammonium acetate for synthesis of hexahydroquinoline derivatives.

rsc advances

In situ synthesis of SO3H supported Fe3O4@resorcinol–formaldehyde resin core/shell and its catalytic evaluation towards the synthesis of hexahydroquinoline derivatives in green conditions