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A functional group-tolerant and transition metal-free coupling of novel  N , O - and  N , S -heterocyclic vinyl chlorides, which affords fully carbosubstituted dihydro-1,4-oxazines/thiazines as well as bicyclic morpholines, is described.

rsc advances

Modular synthesis and transition metal-free alkynylation/alkenylation of Castagnoli–Cushman-derivedN,O- andN,S-heterocyclic vinyl chlorides