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Li 3 (Li,Ti 5 )O 12  (LTO) is a stable and safe negative electrode material for Li-ion batteries, and its Na substitute Na 3 (Li,Ti 5 )O 12  (NTO) is a counterpart for the Na-ion battery.

How does the Li-distribution in the 16d sites determine the stability of A3(Li,Ti5)O12 (A = Li and Na)?

How does the Li-distribution in the 16d sites determine the stability of A₃(Li,Ti₅)O₁₂ (A = Li and Na)?