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The Nakamura reaction using the complex, [Cp*Co(CH 3 CN) 3 ][SbF 6 ] 2  as the catalyst has been described. Alkynes on reaction with β-ketoesters afford tetrasubstituted benzenes.

Addition of 1,3-dicarbonyl compounds to terminal alkynes catalyzed by a cationic cobalt(iii) complex