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The low-wavenumber Raman spectra in combination with theoretical calculations  via  solid-state density functional theory (DFT)-D3 are displayed. The vibrational structures and interaction with solvent of poly- l -proline and the oligoproline P12 series are identified.

rsc advances

Investigation of the <i>cis</i>–<i>trans</i> structures and isomerization of oligoprolines by using Raman spectroscopy and density functional theory calculations: solute–solvent interactions and effects of terminal positively charged amino acid residues

Investigation of the cis–trans structures and isomerization of oligoprolines by using Raman spectroscopy and density functional theory calculations: solute–solvent interactions and effects of terminal positively charged amino acid residues