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A simple and efficient method for the synthesis of benzo[4,5]thieno[2,3- c ]pyrroles  via  dearomative [3 + 2] 1,3-dipolar cycloaddition reaction of nitrobenzothiophenes with an  in situ -generated nonstabilized azomethine ylides have been developed.

Dearomative [3 + 2] cycloaddition reaction of nitrobenzothiophenes with nonstabilized azomethine ylides