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A modified alcohol-enhanced 18 F-fluorodeboronation has been developed for the radiosyntheses of [ 18 F]JNJ-46356479 and [ 18 F]FITM. Unlike the [ 18 F]KF/K 222 approach, this method tolerates the presence of sensitive heterocycles in Bpin precursors 4 and 8 allowing a one-step 18 F-fluorodeboronation on the fully automated TRACERlab™ FX FN platform.

rsc advances

A concise method for fully automated radiosyntheses of [18F]JNJ-46356479 and [18F]FITM via Cu-mediated 18F-fluorination of organoboranes