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Norbornene is an efficient motif for blocking the electronic effect of the CC bond to invert the stereochemistry outcome. Then, using the RDA strategy the CC bond was recovered to obtain the target compound with a definite stereochemistry.

Retro Diels Alder protocol for regioselective synthesis of novel [1,2,4]triazolo[4,3-a]pyrimidin-7(1H)-ones