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The first concise and scalable chemical synthesis of three complex α-1,6-linked trehalose-based oligosaccharides, isobemisiose, neosartose, and fischerose, are reported for the first time.

Synthesis of isobemisiose, neosartose, and fischerose: three α-1,6-linked trehalose-based oligosaccharides identified from Neosartorya fischeri