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The use of imines as a H acceptor for Rh( iii )-catalyzed spirocyclization of 3-arylquinoxalinones and alkynes  via  a C–H functionalization/[3 + 2] annulation sequence has been achieved.

Rh(iii)-catalyzed spiroannulation of 3-arylquinoxalin-2(1H)-ones with alkynes: practical access to spiroquinoxalinones