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We report a novel C 2 Al 4 F 6 - 01  with metal–inorganic Al 4 F 6 -scaffolding, which differs from hitherto known bent-CC types, which all involve carbon-based scaffoldings.

Globally stabilized bent carbon–carbon triple bond by hydrogen-free inorganic–metallic scaffolding Al4F6

Globally stabilized bent carbon–carbon triple bond by hydrogen-free inorganic–metallic scaffolding Al₄F₆