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The coordination motif of alkynly with a metal atom is versatile and plays a pivotal role in tailoring the kernel configuration of the atomically precise metal nanoclusters.

Alkynyl- and phosphine-ligated quaternary Au2Ag2 clusters featuring an Alkynyl-AuAg motif for multicomponent coupling

Alkynyl- and phosphine-ligated quaternary Au₂Ag₂ clusters featuring an Alkynyl-AuAg motif for multicomponent coupling