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C–H⋯π interactions and C–H⋯Cl–C van der Waals interactions are dominant in the crystallization of Au 11 (PR 3 ) 7 Cl 3  clusters, resulting in a crystal system transformation.

rsc advances

Polymorphism of Au11(PR3)7Cl3 clusters: understanding C–H⋯π interaction and C–H⋯Cl–C van der Waals interaction on cluster assembly by surface modification