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Four color electrochromism (yellow, magenta, blue, and navy) has been achieved in Cr( iii )-based metallo-supramolecular polymers ( polyCr ), which were synthesized by 1 : 1 complexation of Cr ions and 1,4-di[[2,2′:6′,2′′-terpyridin]-4′-yl]benzene (L).

Reversible four-color electrochromism triggered by the electrochemical multi-step redox of Cr-based metallo-supramolecular polymers