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Herein, the turn-off fluorescence sensor of 2-((4′-(7,8,13,14-tetrahydrodibenzo[ a , i ]phenanthridin-5-yl)-[1,1′-biphenyl]-4-yl)methylene)malanonitrile ( 7 ) was developed for the recognition of CN − ions and studied using different spectroscopic techniques.

Highly sensitive turn-off fluorescent detection of cyanide in aqueous medium using dicyanovinyl-substituted phenanthridine fluorophore